Effects of high-temperature operating conditions on the through-plane gas permeability of gas diffusion layers used in PEFCs

Authors

  • Raja Muhammad Aslam Raja Arif School of Mechanical Engineering, College of Engineering, Universiti Teknologi MARA, Pasir Gudang Campus, Malaysia

DOI:

https://doi.org/10.24191/jaeds.v1i1.3

Keywords:

PEFCs, gas diffusion layer, gas permeability, high-temperature operation

Abstract

In order to simulate the effects of high-temperature operating conditions on the through-plane gas permeability of gas diffusion layers (GDLs) used in polymer electrolyte fuel cells, uncoated and coated GDLs were heated at various temperatures (i.e. 200, 500 and 800 °C). The results show that the through-plane gas permeability of the uncoated GDLs generally increases after higher temperature treatment. However, the coated GDL displays a different trend: the through-plane gas permeability increases with increasing temperature treatment to 200 and 500 °C, but then decreases after heat treatment at 800 and 1000 °C. With the assistance of SEM images, the above results are discussed.

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References

C. Dyer, “Fuel cells for portable applications,” Fuel Cells Bull., no. 42, pp. 9–10, 2002.

E. Carcadea, H. Ene, D. B. Ingham, R. Lazar, L. Ma, M. Pourkashanian, and I. Stefanescu, “A computational fluid dynamics analysis of a PEM fuel cell system for power generation,” Int. J. Numer. Methods Heat Fluid Flow, vol. 17, no. 3, pp. 302–312, 2007.

J. Stumper and C. Stone, “Recent advances in fuel cell technology at Ballard,” J. Power Sources, vol. 176, no. 2, pp. 468–476, Feb. 2008.

K. Sopian and W. R. Wan Daud, “Challenges and future developments in proton exchange membrane fuel cells,” Renew. Energy, vol. 31, no. 5, pp. 719–727, Apr. 2006.

M.S. Ismail. L. Ma, K.J. Hughes, D.B. Ingham and M. Pourkashanian, “Effect of PTFE loading of gas diffusion layers on the performance of proton exchange membrane fuel cells running at high-efficiency operating conditions,” Int. J. ENERGY Res., vol. 37, no. 13, pp. 1592–1599, 2013.

A. El-kharouf, A. Chandan, M. Hattenberger, and B. G. Pollet, “Proton exchange membrane fuel cell degradation and testing: review,” J. Energy Inst., vol. 85, no. 4, pp. 188–200, 2012.

K. Jiao and X. Li, “Water transport in polymer electrolyte membrane fuel cells,” Prog. Energy Combust. Sci., vol. 37, no. 3, pp. 221–291, Jun. 2011.

H. Li, Y. Tang, Z. Wang, Z. Shi, S. Wu, D. Song, J. Zhang, K. Fatih, J. Zhang, H. Wang, Z. Liu, R. Abouatallah, and A. Mazza, “A review of water flooding issues in the proton exchange membrane fuel cell,” J. Power Sources, vol. 178, no. 1, pp. 103–117, Mar. 2008.

V. Gurau, M. J. Bluemle, E. S. De Castro, Y. M. Tsou, T. A. Zawodzinski, and J. A. Mann, “Characterization of transport properties in gas diffusion layers for proton exchange membrane fuel cells. 2. Absolute permeability,” J. Power Sources, vol. 165, no. 2, pp. 793–802, 2007.

J. G. Pharoah, “On the permeability of gas diffusion media used in PEM fuel cells,” J. Power Sources, vol. 144, no. 1, pp. 77–82, 2005.

J. T. Gostick, M. W. Fowler, M. D. Pritzker, M. A. Ioannidis, and L. M. Behra, “In-plane and through-plane gas permeability of carbon fiber electrode backing layers,” J. Power Sources, vol. 162, no. 1, pp. 228–238, 2006.

M. S. Ismail, D. Borman, T. Damjanovic, D. B. Ingham, and M. Pourkashanian, “On the through-plane permeability of microporous layer-coated gas diffusion layers used in proton exchange membrane fuel cells,” Int. J. Hydrogen Energy, vol. 36, no. 16, pp. 10392–10402, 2011.

J. Ihonen, M. Mikkola, and G. Lindbergh, “Flooding of Gas Diffusion Backing in PEFCs,” J. Electrochem. Soc., vol. 151, no. 8, p. A1152, 2004.

A. Tamayol, F. McGregor, and M. Bahrami, “Single phase through-plane permeability of carbon paper gas diffusion layers,” J. Power Sources, vol. 204, pp. 94–99, 2012.

S. J. Andreasen, J. R. Vang, and S. K. Kær, “High temperature PEM fuel cell performance characterisation with CO and CO2 using electrochemical impedance spectroscopy,” Int. J. Hydrogen Energy, vol. 36, no. 16, pp. 9815–9830, 2011.

J. Lobato, P. Cañizares, M. A. Rodrigo, F. J. Pinar, E. Mena, and D. Úbeda, “Three-dimensional model of a 50 cm2high temperature PEM fuel cell. Study of the flow channel geometry influence,” Int. J. Hydrogen Energy, vol. 35, no. 11, pp. 5510–5520, 2010.

A. Chandan, M. Hattenberger, A. El-Kharouf, S. Du, A. Dhir, V. Self, B. G. Pollet, A. Ingram, and W. Bujalski, “High temperature (HT) polymer electrolyte membrane fuel cells (PEMFC)-A review,” J. Power Sources, vol. 231, pp. 264–278, 2013.

G. Smith, "Oxidation resistance of pyrolytically grown carbon fibers," Carbon, vol. 22, issue 6, pp. 477-479, 1984.

M. S. Ismail, T. Damjanovic, K. Hughes, D. B. Ingham, L. Ma, M. Pourkashanian, and M. Rosli, “Through-Plane Permeability for Untreated and PTFE-Treated Gas Diffusion Layers in Proton Exchange Membrane Fuel Cells,” J. Fuel Cell Sci. Technol., vol. 7, no. 5, p. 051016, 2010.

S. Park, and B.N Popov, “Effect of a GDL based on carbon paper or carbon cloth on PEM fuel cell performance” Fuel, vol. 90, no. 1, pp. 436–440, 2011.

A. El-kharouf, T.J. Mason, DJ.L. Brett, B.G Pollet, “Ex-situ characterisation of gas diffusion layers for proton exchange membrane fuel cells”, Journal of Power Sources, 218, pp. 393-404, 2012.

Toray Carbon Paper 060, Wet Proofed, Fuel Cell Store, July 2021. [Online]. Available: https://www.fuelcellstore.com/fuel-cell-components/gas-diffusion-layers/carbon-paper/toray-carbon-paper/toray-carbon-paper-060.

D. Shou, Y. Tang, L. Ye, J. Fan, and F. Ding, “Effective permeability of gas diffusion layer in proton exchange membrane fuel cells,” Int. J. Hydrogen Energy, vol. 38, no. 25, pp. 10519–10526, 2013.

A. Oshima, Y. Tabata, H. Kudoh, and T. Seguchi, “Radiation induced crosslinking of polytetrafluoroethylene,” Radiat. Phys. Chem., vol. 45, no. 2, pp. 269–273, 1995.

M. S. Ismail, T. Damjanovic, D. B. Ingham, M. Pourkashanian, and A. Westwood, “Effect of polytetrafluoroethylene-treatment and microporous layer-coating on the electrical conductivity of gas diffusion layers used in proton exchange membrane fuel cells,” J. Power Sources, vol. 195, no. 9, pp. 2700–2708, 2010.

R. M. A. Raja Arif, “Water and Thermal Management of PEM Fuel Cells,” Ph.D. dissertation, Department of Mechanical Engineering, Faculty of Engineering, University of Sheffield, 2018. [Online]. Available: http://etheses.whiterose.ac.uk/21899/1/Phd%20Thesis%20Raja.pdf

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Published

2021-09-21

How to Cite

Raja Arif, R. M. A. (2021). Effects of high-temperature operating conditions on the through-plane gas permeability of gas diffusion layers used in PEFCs. Journal of Applied Engineering Design and Simulation, 1(1), 1-11. https://doi.org/10.24191/jaeds.v1i1.3